Sp3 carbon bond angle can be expected is always equal to the tetrahedral 109o28 ', but this can only happen if the four clusters are bound are identical as in methane, neopentana, or carbon tetrachloride. Most cases are found where there has been little deviation from the angles in pure tetrahedarl. As examples of CC-Br angles in 2-bromopropana is 114.2 o. A similar found deviations from the point of 120o to 180o angle to sp2 and sp. This deviation occurs because of slight differences hybridization. Carbon bind the four clusters by using hybrid orbitals of one s orbital and three p orbitals do not actually contain 25% s character and 75%, p for difference electronegativity, each will attract electrons from carbon to him in accordance with electronegativity. Carbon atoms will supply the character when bonded p with more electronegative atoms, as happens in chloromethane. Bond carbon with chlorine exceeds 75% of its p character, and this causes the character p each of the three other bond to less than 75%. In the molecular a tense, more possible bond angles deviate from the ideal angle.
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